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The highly polar character of water makes for interesting interactions between water and nonpolar substances. The statement oil and water don t mix comes to mind. The interaction between water and a nonpolar substance like oil is called the hydrophobic effect or hydrophobic interaction. The interaction does not involve a single, physical force. Nonetheless hydrophobic interactions are sometimes also called hydrophobic forces, because the hydrophobic effect forces molecules to arrange themselves in a way that minimizes the contact between water and the nonpolar substance. Thus, water and oil separate, forming two separate phases; this minimizes the amount of contact between oil molecules and water molecules. The driving force behind hydrophobic interactions is the fact that water likes to form hydrogen bonds. Hydrogen bonding between water and itself or between water and other polar molecules lowers the potential energy. It is thus energetically favorable. When a nonpolar or hydrophobic molecule is placed into water, it takes up space between the water molecules restricting their ability to hydrogen bond with each other. There is a price to pay for this in terms of free energy. First, there is the enthalpy needed to break some of the hydrogen bonds between the water molecules. Second, although hydrogen bonding in water represents a highly ordered, low-entropy state for the molecules (since they must line up with particular orientations to bond with each other), the presence of a nonpolar (hydrophobic) molecule actually decreases the entropy of the water. Remember order in this context is inversely related to the number of ways of doing something. More order means fewer ways of doing something (less entropy). Less order means more ways of doing the same thing (more entropy). Water molecules by themselves are free to rotate and form hydrogen bonds in many orientations. But, at the surface of a nonpolar or hydrophobic molecule, where the water comes in contact with the hydrophobic molecule, steric interactions restrict the water from rotating freely.
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1, The Development of Blu-ray Disc, provides historical context and background, and describes the growing pains of BD as it evolved from DVD. Any top analyst or business leader will tell you that extrapolating from prior technologies is the best way to predict technology trends. This chapter takes a historical stroll through the developments leading up to the introduction of BD.
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Amazon was one of the first companies to offer cloud services to the public, and they are very sophisticated. Amazon offers a number of cloud services, including Elastic Compute Cloud (EC2) your organization. Offers virtual machines and extra CPU cycles for
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Getting Started
The equation of a line in the plane will describe---in compact form---all the points that lie on that line. We determine the equation of a given line by writing its slope in two different ways and then equating them. Some examples best illustrate the idea.
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