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5.6.2 Liquefaction Processes The process options for coal liquefaction can generally be divided into four categories: (a) pyrolysis, (b) solvent extraction, (c) catalytic liquefaction, and (d) indirect liquefaction. Pyrolysis Processes. Pyrolysis of coal dates back to the eighteenth century, using temperatures below 700 C in fixed- or moving-bed reactors. The primary product was a lowvolatile smokeless domestic fuel, although the value of the liquid products was also soon recognized. During the 1920s and 1930s there was a great deal of interest in low-temperature processes, but interest died in the mid-1940s when gas and oil became readily available at low prices. With the oil embargo and increased oil prices of the early 1970s, interest renewed in coal pyrolysis, but in the 1980s interest has again declined along with petroleum prices (Khan and Kurata, 1985). The first category of coal liquefaction processes, pyrolysis processes, involves heating coal to temperatures in excess of 400 C (752 F), which results in the conversion of the coal to gases, liquids, and char. The char is hydrogen deficient thereby enabling intermolecular or intramolecular hydrogen transfer processes to be operative, resulting in relatively hydrogen-rich gases and liquids. Unfortunately, the char produced often amounts to more than 45 percent by weight of the feed coal and, therefore, such processes have often been considered to be uneconomic or inefficient use of the carbon in the coal. In the presence of hydrogen (hydrocarbonization) the composition and relative amounts of the products formed may vary from the process without hydrogen but the yields are still very much dependent upon the process parameters such as heating rate, pressure, coal type, coal (and product) residence time, coal particle size, and reactor configuration. The operating pressures for pyrolysis processes are usually less than 100 psi [690 kPa; more often between 5 and 25 psi (34 172 kPa)] but the hydrocarbonization processes require hydrogen pressures of the order of 300 to 1000 psi (2.1 6.9 MPa). In both categories of process, the operating temperature can be as high as 600 C (1112 F). There are three types of pyrolysis reactors that are of interest: (a) a mechanically agitated reactor, (b) an entrained-flow reactor, and (c) a fluidized bed reactor. The agitated reactor may be quite complex but the entrained-flow reactor has the advantage of either down- or up-flow operation and can provide short residence times. In addition, the coal can be heated rapidly, leading to higher yields of liquid (and gaseous) products that may well exceed the volatile matter content of the coal as determined by the appropriate test (Kimber and Gray, 1967). The short residence time also allows a high throughput of coal and the potential for small reactors. Fluidized reactors Equipment
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